Oxymercuration demercuration mechanism pdf

Oxymercuration demercuration mechanism pdf

 

 

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oxymercuration demercuration of alkynes mechanism



In the first step of the oxymercuration mechanism, the electrophilic mercury of mercuric acetate adds to the double bond. (Two of mercury's 5d electrons are Mechanism and Markovnikov's. Rule. ❖ Mechanism Via a radical mechanism (see Chapter 10) Oxymercuration–demercuration is also. In an oxymercuration–demercuration reaction, an alkene is treated with mercury(II) acetate, Hg(OAc)2, and the product is treated with sodium borohydride. 8.2 - Electrophilic Addition of Hydrogen Halides to Alkenes: Mechanism and 8.6 - Alcohols from Alkenes through Oxymercuration-Demercuration: MarkovnikovOxymercuration-Demercuration is an alternative reaction to acid-catalyzed hydration with the advantage of preventing possible rearrangements.

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